33204-48-7Relevant articles and documents
High iso Aldehyde Selectivity in the Hydroformylation of Short-Chain Alkenes
Iu, Leo,Fuentes, José A.,Janka, Mesfin E.,Fontenot, Kevin J.,Clarke, Matthew L.
supporting information, p. 2120 - 2124 (2019/01/25)
The hydroformylation of propene to give predominantly iso-butanal has been achieved; class-leading selectivity is possible even at higher temperatures that deliver fast conversion. Racemic rhodium complexes of bidentate phospholane phosphites derived from tropos-biphenols and unusual solvent systems are the key to the selectivity observed.
Asymmetric Hydroformylation of 1,2-Disubstituted Olefins Catalysed by Chiral Phosphinephosphite-Rhodium(I) Complexes
Sakai, Nozomu,Nozaki, Kyoko,Takaya, Hidemasa
, p. 395 - 396 (2007/10/02)
Hydroformylations of internal olefins such as (E)- and (Z)-but-2-ene, (E)- and (Z)-1-phenylprop-1-ene, indene, and 1,2-dihydronaphthalene catalysed by (R,S)-binaphos-RhI complex phosphite> or its enantiomer gave the corresponding oxoaldehydes in up to 97percent enantiomeric excess, e.e.
TOTAL SYNTHESIS OF (-)-BETAENONE C
Ichihara, Akitami,Miki, Shokyo,Kawagishi, Hirokazu,Sakamura, Sadao
, p. 4551 - 4554 (2007/10/02)
Stereoselctive synthesis of (-)-betaenone C through intramolecular Diels-Alder reaction has made possible to provide pertinent intermediates for the biosynthetic study of betaenones.