51863-47-9

Basic information

• Product Name: (diethoxyphosphoryl)-phenyl-acetic acid methyl ester
• Synonyms: (diethoxyphosphoryl)-phenyl-acetic acid methyl ester
• CAS NO: 51863-47-9
• Molecular Weight: 286.265
• Mol File: 51863-47-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (diethoxyphosphoryl)-phenyl-acetic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (diethoxyphosphoryl)-phenyl-acetic acid methyl ester(51863-47-9)
• EPA Substance Registry System: (diethoxyphosphoryl)-phenyl-acetic acid methyl ester(51863-47-9)

Safety Data

• Hazardous Substances Data: 51863-47-9(Hazardous Substances Data)

Upstream product

• 22979-35-7 Methyl phenyldiazoacetate 
• 762-04-9 phosphonic acid diethyl ester 
• 18793-81-2 methyl 2-phenyl-2-(2-tosylhydrazono)acetate 
• 37167-62-7 bromo-phenyl-acetic acid methyl ester 
• 122-52-1 triethyl phosphite 
• 67-56-1 methanol 
• 103-82-2 phenylacetic acid 

Downstream Products

• 549546-05-6 C₁₃H₁₂O₄ 
• 33121-49-2 C₁₁H₁₀O₃ 
• 33121-50-5 4-(bromomethyl)-3-phenylfuran-2(5H)-one 
• 1620135-95-6 tert-butyl N-allyl-N-[(2-oxo-3-phenyl-5H-furan-4-yl)methyl]-carbamate 
• 1620135-94-5 tert-butyl N-allyl-N-[(2-oxo-3-phenyl-5H-furan-4-yl)methyl]-carbamate 
• 38654-91-0 2-(diethoxyphosphino)-2-phenylacetic acid 
• 1620136-28-8 3-acetoxy-2-oxopropyl 2-(diethoxyphosphoryl)-2-phenylacetate 
• 1620136-11-9 C₂₀H₁₉NO₂ 
• 1620136-12-0 tert-butyl 2-phenylallyl[(3-phenyl-2-oxo-5H-furan-4-yl)-methyl]carbamate 
• 1037240-58-6 C₁₅H₁₃NO₃ 
• 1037240-61-1 C₁₅H₁₃NO₃ 
• 323185-55-3 cis-2-(1H-pyrrol-1-yl)-α-phenylcinnamic acid 

Relevant articles and documents

Oxidative Dephosphorylation of Benzylic Phosphonates with Dioxygen Generating Symmetrical trans-Stilbenes

Under a dioxygen atmosphere, benzylphosphonates and related phosphoryl compounds can readily produce the corresponding trans-stilbenes in high yields with high selectivity upon treatment with bases. Various functional groups were tolerable under the reaction conditions.

Continuous-flow generation of diazoesters and their direct use in S-H and P-H insertion reactions: Synthesis of α-sulfanyl, α-sulfonyl, and α-phosphono carboxylates

The synthesis of α-sulfanyl, α-sulfonyl, and α-phosphono carboxylates has been achieved using a two-step procedure involving the in-flow generation of diazoesters from sulfonylhydrazones, via Bamford-Stevens elimination, and then subsequent S-H, sulfinate

Polycondensed heterocycles. Part 11: Preparation and regioselective reductions of 5-phenyl-4H-pyrrolo[1,2-α][1]benzazepin-4-one

The Wadsworth-Emmons olefination between 2-(1H-pyrrol-1-yl)benzaldehyde and methyl α-(diethylphosphonyl)phenyl-acetate leads exclusively to the cis-isomer of methyl 2-(1H-pyrrol-1-yl)-α-phenylcinnamate, which, after transformation into the corresponding a