65682-02-2Relevant articles and documents
Oxidative cross-coupling of vinylsilanes in water
Cicco, Stefania R.,Martinelli, Carmela,Pinto, Vita,Naso, Francesco,Farinola, Gianluca M.
, p. 15 - 20 (2013/06/27)
Palladium-promoted cross-dimerization reaction of alkenylsilanes is reported for the first time, which is also one of the very first studies on oxidative cross-coupling between vinylic organometallic reagents. The reaction occurs at room temperature in aqueous micelles and represents a convenient access to all-trans push-pull butadienes.
"Head-to-head" dimerization and dehydrodimerization of vinyl ketones catalyzed by modified rhodium(I) complexes
Kovalev, I. P.,Kolmogorov, Yu. N.,Strelenko, Yu. A.,Ignatenko, A. V.,Vinogradov, M. G.,Nikishin, G. I.
, p. 125 - 133 (2007/10/02)
The dimerization of vinyl ketones RC(O)CH=CH2, I (R = Me, tBu, Ph, p-MeC6H4, cyclopropyl, 2-(5-methylfuryl)) at 80 deg C in the presence of the catalytic system 2-MCl2 leads preferably to either α,β-unsaturated 1,6-diketones RC(O)C