92863-46-2

Basic information

• Product Name: 2-Propenoic acid, 2-methyl-3-phenyl-, butyl ester
• CAS NO: 92863-46-2
• Molecular Formula: C14H18O2
• Molecular Weight: 218.296
• Mol File: 92863-46-2.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 2-methyl-3-phenyl-, butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 2-methyl-3-phenyl-, butyl ester(92863-46-2)
• EPA Substance Registry System: 2-Propenoic acid, 2-methyl-3-phenyl-, butyl ester(92863-46-2)

Safety Data

• Hazardous Substances Data: 92863-46-2(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 97-88-1 2-methyl-butyl acrylate 
• 591-50-4 iodobenzene 
• 1504-55-8 (E)-3-phenyl-2-methyl-2-propenol 
• 71-36-3 butan-1-ol 
• 108-90-7 chlorobenzene 
• 1188274-48-7 butyl (E)-2-methyl-3-(p-toluenesulfonyloxy)prop-2-enoate 
• 98-80-6 phenylboronic acid 
• 1188274-49-8 butyl (Z)-2-methyl-3-(p-toluenesulfonyloxy)prop-2-enoate 
• 2327-99-3 1-phenylpropadiene 
• 201230-82-2 carbon monoxide 
• 37952-93-5 N-benzoyl saccharin 
• 98-88-4 benzoyl chloride 

Relevant articles and documents

Mechanochemical Oxidative Heck Coupling of Activated and Unactivated Alkenes: A Chemo-, Regio- and Stereo-Controlled Synthesis of Alkenylbenzenes

In this work, we present an efficient mechanochemical strategy for chemo-, regio- and stereo-selective oxidative Heck coupling of readily accessible arylboron reagents/heteroaromatics with cyclic and acyclic olefins. Mono- and bis-arylation were achieved without the need of ligands, directing groups or prefunctionalized alkenes, and the reaction chemo-selectivity could be controlled by tuning of the oxidative system. This protocol offers the synthesis of alkenylbenzenes in broad substrate scope, satisfactory yields and excellent selectivity even in the gram scale. (Figure presented.).

N-Acylsaccharins as Amide-Based Arylating Reagents via Chemoselective N-C Cleavage: Pd-Catalyzed Decarbonylative Heck Reaction

Palladium-catalyzed decarbonylative Heck reaction of amides by chemoselective N-C activation using N-acylsaccharins as coupling partners has been accomplished. These studies represent only the second example of amide-Heck reactions reported to date. A broad range of electronically diverse amide and olefin coupling partners is amenable to this transformation. Orthogonal site-selective Heck cross-couplings by C-Br/N-C cleavage and mechanistic studies are reported. This report introduces readily available, bench-stable, cheap, and benign N-acylsaccharins as aryl transfer reagents to access versatile aryl-metal intermediates.

Ligand-Controlled Palladium-Catalyzed Alkoxycarbonylation of Allenes: Regioselective Synthesis of α,β- and β,γ-Unsaturated Esters

The palladium-catalyzed regioselective alkoxycarbonylation of allenes with aliphatic alcohols allows to produce synthetically useful α,β- and β,γ-unsaturated esters in good yields. Efficient selectivity control is achieved in the presence of appropriate ligands. Using Xantphos as the ligand, β,γ-unsaturated esters are produced selectively in good yields. In contrast, the corresponding α,β-unsaturated esters are obtained with high regioselectivity in the presence of PPh2Py as the ligand. Preliminary mechanistic studies revealed that these two catalytic processes proceed by different reaction pathways. In addition, this novel protocol was successfully applied to convert an industrially available bulk chemical, 1,2-butadiene, into dimethyl adipate, which is a valuable feedstock for polymer and plasticizer syntheses, with high yield and TON (turnover number).