1,1,2,2-Tetrahydroperfluorohexadecyl acrylate

Base Information

• Chemical Name: 1,1,2,2-Tetrahydroperfluorohexadecyl acrylate
• CAS No.: 34362-49-7
• Molecular Formula: C19H7 F29 O2
• Molecular Weight: 818.217
• European Community (EC) Number: 251-963-0
• UNII: B6GJ2WKF4H
• DSSTox Substance ID: DTXSID6067836
• Nikkaji Number: J26.242K
• Wikidata: Q27274436
• Mol file: 34362-49-7.mol

Synonyms:34362-49-7;1,1,2,2-Tetrahydroperfluorohexadecyl acrylate;perfluorotetradecylethyl acrylate;UNII-B6GJ2WKF4H;B6GJ2WKF4H;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,16-Nonacosafluorohexadecyl acrylate;EINECS 251-963-0;2-(perfluorotetradecyl)ethyl acrylate;2-Propenoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,16-nonacosafluorohexadecyl ester;Acrylic acid, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,16-nonacosafluorohexadecyl ester;SCHEMBL1537033;DTXSID6067836;C19H7F29O2;C19-H7-F29-O2;Acrylic acid 2-(nonacosafluorotetradecyl)ethyl ester;Q27274436

Chemical Property of 1,1,2,2-Tetrahydroperfluorohexadecyl acrylate

Chemical Property:

• Vapor Pressure: 0.000282mmHg at 25°C
• Boiling Point: 322.3°Cat760mmHg
• Flash Point: 143.9°C
• PSA: 26.30000
• Density: 1.638g/cm³
• LogP: 9.92690
• XLogP3: 10.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 31
• Rotatable Bond Count: 17
• Exact Mass: 817.9982962
• Heavy Atom Count: 50
• Complexity: 1260

Purity/Quality:

99% ^*data from raw suppliers

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,16-NONACOSAFLUOROHEXADECYL ACRYLATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC(=O)OCCC(C(C(C(C(C(C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F

Technology Process of 1,1,2,2-Tetrahydroperfluorohexadecyl acrylate

There total 2 articles about 1,1,2,2-Tetrahydroperfluorohexadecyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

polytetrafluoroethylene (116-14-3,82785-14-6) + ethene (74-85-1) + Pentafluoroethyl iodide (354-64-3) + potassium acrylate (10192-85-5) → 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluoro-tetradecyl acrylate (34395-24-9) + 1H,1H,2H-perfluoro-1-tetradecene + C14F29CH=CH2 (104564-28-5) + C16F33CH=CH2 + 1H,1H,2H,2H-perfluorohexadecan-1-ol (60699-51-6) + C14F29CH2CH2OCOCH=CH2 (34362-49-7) + C16F33CH2CH2OCOCH=CH2 + C18F37CH2CH2OCOCH=CH2 (65104-64-5) + 2-(perfluorodecyl)ethanol (865-86-1) + 1H,1H,2H-perfluorodecene (21652-58-4) + 1H,1H,2H,2H-perfluorobutadecan-1-ol (39239-77-5) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol (678-39-7) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene (30389-25-4) + 1H,1H,2H,2H-heptadecafluorodecyl acrylate (27905-45-9) + 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-propenoate (17527-29-6) + 1,1,2,2-Tetrahydroperfluorododecyl acrylate (17741-60-5)

Guidance literature:

polytetrafluoroethylene; Pentafluoroethyl iodide; copper catalyst; at 80 ℃; under 6000.6 Torr;

ethene; copper catalyst; at 100 ℃; for 3h; under 2250.23 Torr;

potassium acrylate; With 4-methoxy-phenol; hydroquinone; In tert-butyl alcohol; at 180 - 190 ℃; for 6h; Product distribution / selectivity;

Reference yield:

1H,1H,2H,2H-perfluorohexadecan-1-ol (60699-51-6) + 1H,1H,2H,2H-perfluorooctadecan-1-ol (65104-67-8) + 2-(perfluorodecyl)ethanol (865-86-1) + 1H,1H,2H,2H-perfluorobutadecan-1-ol (39239-77-5) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol (678-39-7) + acrylic acid (79-10-7) → 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluoro-tetradecyl acrylate (34395-24-9) + C14F29CH2CH2OCOCH=CH2 (34362-49-7) + C16F33CH2CH2OCOCH=CH2 + 1H,1H,2H,2H-heptadecafluorodecyl acrylate (27905-45-9) + 1,1,2,2-Tetrahydroperfluorododecyl acrylate (17741-60-5)

Guidance literature:

With hydroquinone; toluene-4-sulfonic acid; In toluene; for 4h; Product distribution / selectivity;

upstream raw materials:

1H,1H,2H,2H-perfluorohexadecan-1-ol

1H,1H,2H,2H-perfluorooctadecan-1-ol

2-(perfluorodecyl)ethanol

1H,1H,2H,2H-perfluorobutadecan-1-ol

Refernces

• 1、 -. "PROCESS FOR PRODUCING FLUORINATED (METH)ACRYLIC ESTER". Page/Page column 9-10. . Retrieved 2010/11/25.